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No. USB 3.0 uses different connect pins from USB 2.0's. The USB 3.0 Standard-B receptacle interfaces are divided into two sets of interfaces: the USB 2.0 interface and the USB 3.0 SuperSpeed interface. The USB 2.0 interface is comprised of pins 1 to 4, and the USB 3.0 SuperSpeed interface is comprised of pins 5 to 9. The figure below shows the footprint of USB3.0 found in "Universal Serial Bus 3.0 Specification Version 1.0_Page 5-19_Figure5-8".